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Make sure you have your free credit monitoring signed up. It will be good until the end of the year.
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Make sure to buy a copy of Microsoft office from Corporateperks. $9.95 if you download it. You'll need it to work on your resume.
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If you are on corporate phone plan, consider buying a new phone before you switch to personal paid plan. The corporate discounts are pretty good.
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Check to make sure any of your affinity programs (hotel, airline etc.) have personal e-mail address instead of Cisco address.
Others can feel free to add to this list.